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There’s a surprise flourish to Chuck’s love life when he connects with a fetching woman (Rachel Bilson) and squires Sarah on a date. On the espionage front, Chuck tangles with a poison virtuoso who’s out to control nuclear facilities.

Mason Whitney is tied down in Riordan Payne’s lair. Riordan has given him a fatal, time-released dose of a truth-telling drug. As soon as Mason reveals where he’s hidden the codes, Riordan promises to administer an antidote. In the supply closet at Wienerlicious, Chuck and Sarah rehearse for a sushi dinner date with Ellie and Captain Awesome. When Sarah’s boss Scooter knocks, Sarah opens her blouse and jumps Chuck.

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